Pre-Twentieth Century Timeline of Chemical and
Biological Weapons
Biological and chemical weapons were not a twentieth century invention. In one form or another, militaries have employed biological and chemical agents for millennia. The following outline provides a brief overview of the pre-twentieth century history of such warfare. It is by no means an exhaustive summary, but a representative sample of the strategies used prior to World War I.
Ø 7th
century BC - Assyrians used ergot (a
fungal disease of rye) to poison water supplies. The fungus produces a natural hallucinogen
related to LSD that also induces a disease widely known in later times as St Anthonys Fire.
Ø c.600BC - The purgative hellebore was used during the siege of Cirrha, the
Ø 500BC - A burning mixture of wood, pitch and sulphur was used to incapacitate
a beleaguered Athenian force prior to assault.
Ø 431-404BC - Peloponnesian War. Arsenic smoke was used during the sieges of

Warriors from the Pelopponesian
War
Source: http://homepages.uc.edu/~fitzsiry/civhist.html
Ø 184BC -
Ø 82-72BC - Romans used toxic smoke against the Charakitanes
in
Ø 1155 - Siege of
Ø 1346 - Tartar army catapulted corpses of plague victims over the city
walls in siege of Kaffa - supposed origin of Black
Death in
Ø c.1500 - Leonardo da Vinci devised a chemical
weapon: a mixture of powdered arsenic and powdered sulphur packed into shells
to be fired against ships.
Ø 1650 - Polish artillery general Siemenowics
fired spheres filled with the saliva of rabid dogs at his enemies.
Ø 1675 - Article 57 of Strasbourg Agreement of 27 August between French
and German armies directed that neither side should use poisoned bullets. This was the first international agreement in
modern history in which use of such weapons was prohibited.
Ø 1797 - Napoleon attempted to infect the inhabitants of the besieged
city of

Napoleon Bonaparte
source: http://www.theotherside.co.uk/tm-heritage/background/napoleon.htm
Ø 1812 - Capt. Thomas Cochrane RN submitted his plans for chemical weapons
to be used in the Napoleonic War to a secret committee headed by the Duke of
York.
Ø 1845 - Use of green wood smoke by General Pilissier
in Ouled Ria
resulted in the massacre of the Kabyl tribe.
Ø 1855 - British War Department considered shells containing cacodyl and cacodyl oxide mixed
with self-igniting liquid for use in Crimean War. Admiral Cochrane proposed the use of ships to
disperse poison gas based on sulphur and charcoal during the siege of the
Russian garrison at Sevastopol.
Ø 1874 - Conference of Brussels, held as a result of Russian initiative,
reached an agreement prohibiting the use of poisons or poisonous weapons -
Brussels Declaration.
Ø 1899 - Hague Declaration prohibited poison or poisoned arms. Twenty
seven states finally ratified this treaty, including Russia (although no longer
bound) and UK which finally signed in 1907. The United States did not sign.
Sources: http://www.mod.uk/issues/cbw/history.htm
http://my.webmd.com/content/article/61/67268.htm